Annuaire
Nous Contacter
Accueil du site > Personnel > Permanents > Eric CLOT
Page Personnelle de Eric CLOT
 |
Directeur de Recherches 2nde Classe - CNRS
Catalyse et Interfaces Institut Charles GERHARDT - CNRS 5253
Contact : Eric.Clot@univ-montp2.fr |
Collaborations
Publications Conférences Invitées Communications orales Enseignement |
Parcours
HDR : "Modélisation de la Structure et de la Réactivité en Chimie Organométallique : La Richesse du Dialogue Expérience / Théorie.", Université Montpellier 2 (Juin 2004).
ATER à l’ENS Lyon (1995-1996).
Doctorat : "Conséquences de la Présence de Particules Identiques sur la Structure et la Dynamique de Polyhydrures de Métaux de Transition.", Université Paris Sud Orsay (Directeurs : Odile Eisenstein et Claude Leforestier, Juin 1995).
Service National : Professeur de Physique-Chimie au Lycée Militaire d’Aix en Provence (1991-1992).
DEA Physico-Chimie Moléculaire, Université Paris Sud Orsay (1990-1991).
Agrégation de Chimie (1990).
Magistère des Sciences de la Matière, ENS Lyon (1987-1990).
Thèmes de Recherche
- Activation et Fonctionnalisation de Liaisons Inertes en Catalyse Homogène
- Arylation directe.
- Couplage C-C décarboxylant.
- Diamination à partir d’hydrazides.
- Deshydrogénation des amines-boranes.
- Modélisation de la Compléxité du Système Catalytique
- Influence des contre-ions.
- Influence stérique des ligands ancillaires.
- Rôle du Solvant.
- Nature de la Liaison Métal-Ligand
- Corrélation Energies de Liaison Organique / Inorganique.
- Analyse NBO de la Structure Electronique.
- Quantification de l’Effet Donneur des Ligands.
Collaborations
- Sylviane Sabo-Etienne, LCC Toulouse
- Réactivité de polyhydrures du ruthénium
- Deshydrogénation catalytique d’amine-boranes (ANR Hybocat 2009-20012)
- Philip Mountford, Oxford University
- Réactivité de Complexes Imido du Titane : Polymérisation
- Réactivité de Complexes Hydrazido du Titane : Diamination des Alcynes (Grant EPRSC 2009-2012)
- Olivier Baudoin, Université de Lyon
- Activation C(sp3)-H catalysée au Palladium (ANR AlCaCHa 2008-2011)
- Jennifer Love, University of British Columbia
- Couplages croisés catalytiques
- Martin Albrecht, University of Dublin
- Processus d’activation C-H
Articles dans des revues à comité de lecture
Synthesis, Bonding and Reactivity of a Terminal Titanium Alkylidene Hydrazido Compound,
Chemistry - A European Journal, 19, 2013, 4198-4216
Ligand-controlled β-selective C(sp3)-H arylation of N-Boc-piperidines,
Chemical Science, 4, 2013, 2241-2247
Synthesis of a ruthenium bis(diisopropylamino(isocyano)borane) complex from the activation of an amino(cyano)borane,
Dalton Transactions, 42, 2013, 776-781
Hydride Ligands Make the Difference, Density Functional Study of the Mechanism of the Murai Reaction Catalyzed by [Ru(H)2(H2)2(PR3)2] (R=cyclohexyl),
Chemistry - A European Journal, 18, 2012, 11449-11458
Site selectivity and reversibility in the reactions of titanium hydrazides with Si-H, Si-X, C-X and H+ reagents, Ti=Nα 1,2-silane addition, Nβ alkylation, Nα protonation and σ-bond metathesis,
Dalton Transactions, 41, 2012, 2277-2288
On the Mechanism of the Palladium-Catalyzed β-Arylation of Ester Enolates,
Chemistry - A European Journal, 18, 2012, 1932-1944
Titanium tert-Butoxyimido Compounds,
Inorganic Chemistry, 50, 2011, 12155-12171
Ruthenium agostic (phosphinoaryl)borane complexes, multinuclear solid-state and solution NMR, X-ray and DFT studies,
Journal of the American Chemical Society, 133, 2011, 17232-17238
Dimethylaminoborane (H2BNMe2) coordination to late transition metal centers, snapshots of the B-H oxidative addition process,
Inorganic Chemistry, 50, 2011, 11039-11045
C-F and C-H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers, How Fluorine Tips the Scales,
Accounts of Chemical Research, 44, 2011, 333-348
Titanium alkoxyimido (Ti=N-OR) complexes, reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands,
Chemical Communications, 47, 2011, 4926-4928
New Sandwich and Half-Sandwich Titanium Hydrazido Compounds,
Organometallics, 30, 2011, 2295-2307
Reactions of Cyclopentadienyl-Amidinate Titanium Hydrazides with CO2, CS2, and Isocyanates, Ti=Nα Cycloaddition, Cycloaddition-Insertion, and Cycloaddition-NNR2 Group Transfer Reactions,
Organometallics, 30, 2011, 1182-1201
Si-H and Si-Cl bond activation reactions of titanium hydrazides with silanes and subsequent Ti-H/E-H (E = Si or H) σ-bond metathesis,
Chemical Communications, 47, 2011, 3147-3149
Reaction site diversity in the reactions of titanium hydrazides with organic nitriles, isonitriles and isocyanates, Ti=Nα cycloaddition, Ti=Nα insertion and Nα-Nβ bond cleavage,
Chemistry - A European Journal, 17, 2011, 265-285
Mechanistic investigation of vinylic carbon-fluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF,
Journal of Fluorine Chemistry, 131, 2010, 1122-1132
Ruthenium, Rhodium, and Iridium Bis(σ-B-H) Diisopropylaminoborane Complexes+,
Organometallics, 29, 2010, 5591-5595
Synthesis, structure, and reductive elimination in the series Tp'Rh(PR3)(ArF)H; Determination of rhodium-carbon bond energies of fluoroaryl substituents,
Dalton Transactions, 39, 2010, 10495-10509
DFT study of the mechanism of benzocyclobutene formation by palladium-catalysed C(sp3)-H activation, role of the nature of the base and the phosphine,
Dalton Transactions, 39, 2010, 10528-10535
Importance of palladium-carbon bond energies in direct arylation of polyfluorinated benzenes,
Dalton Transactions, 39, 2010, 10510-10519
Palladium-Catalyzed β-Arylation of Carboxylic Esters,
Angewandte Chemie International Edition, 49, 2010, 7261-7265
Intramolecular Palladium-Catalyzed Alkane C-H Arylation from Aryl Chlorides,
Journal of the American Chemical Society, 132, 2010, 10706-10716
M═Nα Cycloaddition and Nα−Nβ Insertion in the Reactions of Titanium Hydrazido Compounds with Alkynes: A Combined Experimental and Computational Study,
Journal of the American Chemical Society, 132, 2010, 10484-10497
Diels-Alder reaction of vinylene carbonate and 2,5-dimethylfuran, kinetic vs. thermodynamic control,
New Journal of Chemistry, 34, 2010, 517-525
C-H bond activation in transition metal species from a computational perspective,
Chemical Reviews, 110, 2010, 749-823
Ruthenium bis(σ-B-H) aminoborane complexes from dehydrogenation of amine-boranes, trapping of H2B-NH2,
Angewandte Chemie International Edition, 49, 2010, 918-920
Single and double substrate insertion into the Ti=Nα bonds of terminal titanium hydrazides,
Chemical Communications, , 2010, 85-87
Synthesis and structure of "16-electron" rhodium(III) catalysts for transfer hydrogenation of a cyclic imine, mechanistic implications,
Chemical Communications, , 2009, 6801-6803
Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp'Rh(CNneopentyl)] Complex,
Journal of the American Chemical Society, 131, 2009, 13464-13473
Reactions of cyclopentadienyl-amidinate titanium imido compounds with CO2: cycloaddition-extrusion versus cycloaddition-insertion,
Dalton Transactions, , 2009, 5960-5979
Ion-pairing in organometallic chemistry: structure and influence on proton transfer from a computational perspective,
European Journal of Inorganic Chemistry, , 2009, 2319-2328
Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations,
Journal of the American Chemical Society, 131, 2009, 7817-7827
Phosphinoborane and sulfidoborohydride as chelating ligands in polyhydride ruthenium complexes, agostic σ-borane versus dihydroborate coordination,
Angewandte Chemie International Edition, 48, 2009, 2964-2968
Synthesis and ethylene polymerization capability of metallocene-like imido titanium dialkyl compounds and their reactions with AliBu3,
Organometallics, 25, 2006, 5549-5565
Self-aggregation tendency of all species involved in the catalytic cycle of bifunctional transfer hydrogenation,
Organometallics, 28, 2009, 960-967
Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study,
Organometallics, 27, 2008, 6479-6494
Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes, coupling of Ti=NNPh2 with PhCCMe, PhCCH, MeCN and tBuCP,
Chemical Communications, , 2008, 5101-5103
Ti=NR vs. Ti-R' functional group selectivity in imido titanium alkyl cations from a DFT perspective,
Organometallics, 27, 2008, 6111-6122
Synthesis of benzocyclobutenes by palladium-catalyzed C-H activation of methyl groups, method and mechanistic study,
Journal of the American Chemical Society, 130, 2008, 15157-15166
Ti=NR vs. Ti-R' functional group selectivity in imido titanium alkyl cations from an experimental perspective,
Organometallics, 27, 2008, 6096-6110
A terminal borylene ruthenium complex, from B-H activation to reversible hydrogen release,
Journal of the American Chemical Society, 130, 2008, 12878-12879
A NMR, X-ray, and DFT combined study on the regio-chemistry of nucleophilic addition to platinium(II) coordinated terminal olefins,
Journal of Organometallic Chemistry, 693, 2008, 2819-2827
Syntheses, Reactivity and DFT Studies of Group 2 and Group 12 Metal Complexes of Tris(pyrazolyl)methanides Featuring "Free" Pyramidal Carbanions,
Chemistry - A European Journal, 14, 2008, 5918-5934
Synthesis, DFT Studies, and Reactions of Scandium and Yttrium Dialkyl Cations Containing Neutral fac-N3 and fac-S3 Donor Ligands,
Organometallics, 27, 2008, 3458-3473
Mechanism of Homogeneous Iridium-Catalyzed Alkylation of Amines with Alcohols from a DFT Study,
Organometallics, 27, 2008, 2529-2535
β-H transfer from the metallacyclobutane, a key step in the deactivation and byproduct formation for the well-defined silica-supported rhenium alkylidene alkene metathesis catalyst,
Journal of the American Chemical Society, 130, 2008, 6288-6297
A weak donor, planar chelating bitriazole N-heterocyclic carbene ligand for ruthenium(II), palladium(II), and rhodium,
Organometallics, 27, 2008, 2128-2136
Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations,
Journal of the American Chemical Society, 130, 2008, 5886-5900
Stereochemical nonrigidity of a chiral rhodium boryl hydride complex, a σ-borane complexe as transition state for isomerization.,
Journal of the American Chemical Society, 130, 2008, 4375-4385
Aliphatic versus Aromatic C-H Activation in the Formation of Abnormal Carbenes with Iridium, A Combined Experimental and Theoretical Study,
Organometallics, 26, 2007, 5304-5314
Imidazolium Carboxylates as Versatile and Selective N-Heterocyclic Carbene Transfer Agents, Synthesis, Mechanism, and Applications,
Journal of the American Chemical Society, 129, 2007, 12834-12846
New ligand platforms for developing the chemistry of the Ti=N-NR2 functional group and the insertion of alkynes into the N-N bond of a Ti=N-NPh2 ligand,
Chemical Communications, , 2007, 4937-4939
Mesitylborane as a Bis(σ-B-H) Ligand, An Unprecedented Bonding Mode to a Metal Center,
Journal of the American Chemical Society, 129, 2007, 8704-8705
Interionic Structure of Ion Pairs and Ion Quadruples of Half-Sandwich Ruthenium(II) Salts Bearing -Diimine Ligands,
Organometallics, 26, 2007, 3930-3946
Understanding d0-Olefin Metathesis Catalysts, Which Metal, Which Ligands?,
Journal of the American Chemical Society, 129, 2007, 8207-8216
Computational structure-activity relationships in H2 storage, how placement of N atoms affects release temperatures in organic liquid storage materials,
Chemical Communications, , 2007, 2231-2233
Agostic interaction and intramolecular proton transfer from the protonation of dihydrogen ortho metalated ruthenium complexes,
Proceeding of the national academy of sciences, 104, 2007, 6945-6950
Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between theory and experiment,
Proceeding of the national academy of sciences, 104, 2007, 6939-6944
Aggregation in solution of neutral half-sandwich Ru(II) precatalysts for transfer hydrogenation,
New Journal of Chemistry, 29, 2005, 430-433
Pendant arm functionalized benzamidinate titanium imido compounds: Experimental and computational studies of their reactions with CO2,
Organometallics, 24, 2005, 2347-2367
Reactions of neutral and cationic diamide-supported imido complexes with CO2 and other heterocumulenes: Issues of site selectivity,
Organometallics, 24, 2005, 2368-2385
Well-defined imidotitanium alkyl cations: agostic interactions, migratory insertion vs. [2+2] cycloaddition, and the first structurally authenticated AlMe3 adduct of any transition metal alkyl cation,
Chemical Communications, , 2005, 3313-3315
Structure and reactivity of trans-bis[2-(2-chloroethyl)pyridine]palladium chloride (1). A study on the elimination reaction of 1 and 2-(2-chloroethyl)pyridine induced by quinuclidine in acetonitrile,
The Journal of Organic Chemistry, 70, 2005, 10688-10692
Experimental and DFT studies of cationic imido titanium alkyls: Agostic interactions and C-H bond and solvent activation reactions of isolobal analogues of group 4 metallocenium cations,
Organometallics, 25, 2006, 2806-2825
Carbonyl(center dot center dot center dot)carbonyl interactions in first-row transition metal complexes,
CrystEngComm, 8, 2006, 563-570
AlMe3 and ZnMe2 adducts of an imido titanium methyl cation: a combined crystallographic, spectroscopic and DFT study,
Journal of the American Chemical Society, 128(46) , 2006, 15005-15018
Selectivity in C–Cl bond activation of dichloroarenes by photogenerated Cp*Re(CO)2: combined experimental and DFT studies,
New Journal of Chemistry, 29, 2005, 226-231
DFT calculations of d0 M(NR)(CHtBu)(X)(Y) (M =Mo, W; R = CPh3,2,6-iPr–C6H3; X and Y = CH2tBu, OtBu, OSi(OtBu)3), olefin metathesis catalysts: structural, spectroscopic and electronic properties.,
Dalton Transactions, , 2006, 3077-3087
Understanding Structural and Dynamic Properties of Well-Defined Rhenium-Based Olefin Metathesis Catalysts, Re(CR)(CHR)(X)(Y), from DFT and QM/MM Calculations,
Organometallics, 24, 2005, 1586-1597
An Anion-Dependent Switch in Selectivity Results from a Change of C-H Activation Mechanism in the Reaction of an Imidazolium Salt with IrH5(PPh3)2,
Journal of the American Chemical Society, 127, 2005, 16299-16311
d0 Re-Based Olefin Metathesis Catalysts, Re(CR)(CHR)(X)(Y): The Key Role of X and Y Ligands for Efficient Active Sites,
Journal of the American Chemical Society, 127, 2005, 14015-14025
Validation of the M-C/H-C Bond Enthalpy Relationship through Application of Density Functional Theory,
Journal of the American Chemical Society, 128, 2006, 8350-8357
Conférences Invitées
Activation C-H catalytique: l'apport des études théoriques.,
«Journées Scientifiques 2013 de la Section Bretagne-Pays de la Loire de la SCF», Brest, France, 05-07 mai 2013,
Ruthenium-Borane Complexes: Structure and Reactivity from a Computational Perspective,
«95th Canadian Chemistry Conference», Calgary, Canada, 26-30 mai 2012,
Ruthenium-borane complexes: structure and reactivity from a computational perspective,
«XXVth International Conference on Organometallic Chemistry», Lisbonne, Portugal, 2-7 septembre 2012,
18-electron rule : myth or reality? A Natural Bond Orbital perspective.,
«8th International School of Organometallic Chemistry, ISOC2011», Camerino, Italie, 27-31 août 2011,
DFT Study of the mechanism of palladium-catalysed arylation of carboxylic esters.,
«9th Congress of the World Association of Theoretically Oriented Chemists, WATOC2011», Saint Jacques de Compostelle, Espagne, 17-23 juillet 2011,
DFT Study of the mechanism of PD-catalysed arylation of carboxylic esters.,
«3rd Chinese French Workshop in Theoretical Chemistry», La Colle sur Loup, France, 10-12 octobre 2011,
On the use of dispersion corrections in computational studies of transition metal reactivity,
«Challenges in Computational Homogeneous Catalysis», Stockholm, Suède, 25-26 août 2011,
Transition Metal Catalyzed C-H Activation from a Computational Perspective',
«Innovative Catalysis - New Processes and Selectivities», Ankara, Turquie, 25-27 mai 2010,
Modélisation de l'activation C-H en catalyse homogène: aspects thermodynamiques et cinétique,
«Journées Sherbrooke-Montpellier 2010», Sherbrooke, Canada, 05-08 octobre 2010,
C-H Activation in Homogeneous Catalysis from a Computational Perspective,
«Groupe d'Etude en Chimie Organique 51», La Grande Motte, France, 01-05 septembre 2010,
Selectivity in C-H activation from a computational perspective,
«CERC3 Young Chemists' Workshop on catalytic C-H functionalization of organic molecules», Lyon, France, 05-08 avril 2009,
Apport de la méthode NBO en chimie organométallique,
«IX Journées Thématiques de Chimie Théorique», Marseille, 01 mars 2007,
Carbènes N-hétérocycliques en catalyse: l'apport du théoricien,
«GECOM-CONCOORD 2006», Noirmoutier, France, 20-25 mai 2006,
Counter Ion E ffects on Structure and Reactivity from a DFT Perspective,
«Molecular Crystal Engineering : Euroconference on Evaluations and Predictions of Solid State Materials Properties», Helsinki, Finlande, 21-25 juin 2005,
Communications orales
DFT Study of the mechanism of benzocyclobutene formation by palladium-catalyzed C(sp3)-H activation: role of the nature of the base and the phosphine
«Dalton Discussion 12 Catalytic C-H and C-X Bond Activation», Durham, Angleterre, 12-15 septembre 2010,
A terminal borylene ruthenium complex: from B-H activation to reversible hydrogen release
«Innovative Catalysis - New Processes and Selectivities», Turku, Finlande, 25-28 mai 2009,
Selectivity in C-H activation from a computational perspective
«38th Meeting of the RSC Inorganic Reaction Mechanisms Group», Oxford, Angleterre, 04-06 janvier 2009,
Selectivity in CH activation from a computational perspective
«XXIII International Conference on Organometallic Chemistry», Rennes, France, 13-18 juillet 2008,
Influence of the counter anion in organometallic chemistry from a theoretical perspective
«9th FIGIPAS», Vienne, Autriche, 4-7 juillet 2007,
Agostic interactions and heterobimetallic adducts in cationic imido and metallocenium titanium alkyls from a DFT perspective: analogies and differences."
«XXIIth ICOMC», Saragosse, Espagne, 23-28 juillet 2006,
Theoretical studies of the structure and energetic of ion-pairs and higher order aggregates in transition metal complexes
«Group Meeting COST D24», Lisbonne, Portugal, 21-23 septembre 2006,
Activités d’Enseignement
- DEUG Université Montpellier 2 : Préparation ENSI Chimie : Thermodynamique et Cinétique (1997-2000, 21h/an).
- Préparation Agrégation de Physiques, Université Montpellier 2 : Cours Chimié Générale et Corrections Problèmes (1998-2000, 30h/an).
- DEA PCMET, Université Paul Sabatier : Structure et Réactivité en Chimie Organométallique : Approche Théorique (1999-2002, 15h/an).
- DEA PCT, Université Paul Sabatier : Chimie Théorique Appliquée à l’Etude de la Réactivité (1999-2000, 21h/an).
- Agrégation de Chimie : Membre du Jury (2000-2005).
- Ecole Polytechnique : Professeur Chargé de Cours (depuis 2004, 15h/an)
