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Page Personnelle de Eric CLOT

Directeur de Recherches 2nde Classe - CNRS
Catalyse et Interfaces

Institut Charles GERHARDT - CNRS 5253
Université Montpellier 2 - Bât.15 - CC 1501
Place Eugène Bataillon
34 095 Montpellier Cedex

Contact : Eric.Clot@univ-montp2.fr

Collaborations
Publications
Conférences Invitées
Communications orales
Enseignement

Parcours

- HDR : "Modélisation de la Structure et de la Réactivité en Chimie Organométallique : La Richesse du Dialogue Expérience / Théorie.", Université Montpellier 2 (Juin 2004).
- ATER à l’ENS Lyon (1995-1996).
- Doctorat : "Conséquences de la Présence de Particules Identiques sur la Structure et la Dynamique de Polyhydrures de Métaux de Transition.", Université Paris Sud Orsay (Directeurs : Odile Eisenstein et Claude Leforestier, Juin 1995).
- Service National : Professeur de Physique-Chimie au Lycée Militaire d’Aix en Provence (1991-1992).
- DEA Physico-Chimie Moléculaire, Université Paris Sud Orsay (1990-1991).
- Agrégation de Chimie (1990).
- Magistère des Sciences de la Matière, ENS Lyon (1987-1990).


Thèmes de Recherche

  • Activation et Fonctionnalisation de Liaisons Inertes en Catalyse Homogène
    • Arylation directe.
    • Couplage C-C décarboxylant.
    • Diamination à partir d’hydrazides.
    • Deshydrogénation des amines-boranes.
  • Modélisation de la Compléxité du Système Catalytique
    • Influence des contre-ions.
    • Influence stérique des ligands ancillaires.
    • Rôle du Solvant.
  • Nature de la Liaison Métal-Ligand
    • Corrélation Energies de Liaison Organique / Inorganique.
    • Analyse NBO de la Structure Electronique.
    • Quantification de l’Effet Donneur des Ligands.

Collaborations

  • Philip Mountford, Oxford University
    • Réactivité de Complexes Imido du Titane : Polymérisation
    • Réactivité de Complexes Hydrazido du Titane : Diamination des Alcynes (Grant EPRSC 2009-2012)

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Articles dans des revues à comité de lecture

  • Gudrun T. Plundrich, Hubert Wadepohl, Eric Clot and Lutz H. Gade
    η6-Arene-Zirconium-PNP-Pincer Complexes, Mechanism of Their Hydrogenolytic Formation and Their Reactivity as Zirconium(II) Synthons,
    Chem. Eur. J. 2016, 22, 9283-9292
  • David Balcells, Eric Clot, Odile Eisenstein, Ainara Nova and Lionel Perrin
    Deciphering Selectivity in Organic Reactions: A Multifaceted Problem,
    Acc. Chem. Res. 2016, 49, 1070-1078
  • Torsten Roth, Hubert Wadepohl, Eric Clot and Lutz H. Gade
    Azaphilic versus Carbophilic Coupling at C=N Bonds: Key Steps in Titanium-Assisted Multicomponent Reactions,
    Chem. Eur. J. 2015, 21, 18730-18738
  • Christopher J. Wallis, Gilles Alcaraz, Alban S. Petit, Amalia I. Poblador-Bahamonde, Eric Clot, Christian Bijani, Laure Vendier and Sylviane Sabo-Etienne
    A Highly Effective Ruthenium System for the Catalyzed Dehydrogenative Cyclization of Amine--Boranes to Cyclic Boranes under Mild Conditions,
    Chem. Eur. J. 2015, 21, 13080-13090
  • Laura C. Stevenson, Simona Mellino, Eric Clot and Philip Mountford
    Reactions of Titanium Hydrazides with Silanes and Boranes, N--N Bond Cleavage and N Atom Functionalization,
    J. Am. Chem. Soc. 2015, 137, 10140-10143
  • Philipp M. Holstein, Maria Vogler, Paolo Larini, Guillaume Pilet, Eric Clot and Olivier Baudoin
    Efficient Pd0-Catalyzed Asymmetric Activation of Primary and Secondary C--H Bonds Enabled by Modular Binepine Ligands and Carbonate Bases,
    ACS Catal. 2015, 5, 4300-4308
  • Kate F. Donnelly, Ralte Lalrempuia, Helge Müller-Bunz, Eric Clot and Martin Albrecht
    Controlling the Selectivity of C–H Activation in Pyridinium Triazolylidene Iridium Complexes: Mechanistic Details and Influence of Remote Substituents,
    Organometallics 2015, 34, 858-869
  • Christos E. Kefalidis, Michaël Davi, Philipp M. Holstein, Eric Clot and Olivier Baudoin
    Mechanistic Study of the Selectivity of Olefin versus Cyclobutene Formation by Palladium(0)-Catalyzed Intramolecular C(sp3)--H Activation,
    J. Org. Chem. 2014, 79, 11903-11910
  • Audrey Cassen, Laure Vendier, Jean-Claude Daran, Amalia Poblador-Bahamonde, Eric Clot, Gilles Alcaraz and Sylviane Sabo-Etienne
    B--C Bond Cleavage and Ru--C Bond Formation from a Phosphinoborane, Synthesis of a Bis-σ Borane Aryl-Ruthenium Complex,
    Organometallics 2014, 33, 7157-7163
  • Joseph S. Bair, York Schramm, Alexey G. Sergeev, Eric Clot, Odile Eisenstein and John F. Hartwig
    Linear-Selective Hydroarylation of Unactivated Terminal and Internal Olefins with Trifluoromethyl-Substituted Arenes,
    J. Am. Chem. Soc. 2014, 136, 13098-13101
  • Audrey Cassen, Yann Gloaguen, Laure Vendier, Carine Duhayon, Amalia Poblador-bahamonde, Christophe Raynaud, Eric Clot, Gilles Alcaraz and Sylviane Sabo-Etienne
    B-H, C-H, and B-C Bond Activation, The Role of Two Adjacent Agostic Interactions,
    Angew. Chem. Int. Ed. 2014, 53, 7569-7573
  • Laura R. Groom, Andrew D. Schwarz, Ainara Nova, Eric Clot and Philip Mountford
    Synthesis and Reactions of a Cyclopentadienyl-Amidinate Titanium tert-Butoxyimido Compound,
    Organometallics 2013, 32, 7520-7539
  • Yann Gloaguen, Gaëtan Bénac-Lestrille, Laure Vendier, Ulrike Helmstedt, Eric Clot, Gilles Alcaraz and Sylviane Sabo-Etienne
    Monosubstituted Borane Ruthenium Complexes RuH222-H2BR)(PR'3)2, A General Approach to the Geminal Bis(σ-B-H) Coordination Mode,
    Organometallics 2013, 32, 4868-4877
  • Pei-Jen Tiong, Laura R. Groom, Eric Clot and Philip Mountford
    Synthesis, Bonding and Reactivity of a Terminal Titanium Alkylidene Hydrazido Compound,
    Chem. Eur. J. 2013, 19, 4198-4216
  • Anthony Millet, Paolo Larini, Eric Clot and Olivier Baudoin
    Ligand-controlled β-selective C(sp3)-H arylation of N-Boc-piperidines,
    Chem. Sci. 2013, 4, 2241-2247
  • Maximilian Joost, Gilles Alcaraz, Laure Vendier, Amalia Poblador-Bahamonde, Eric Clot and Sylviane Sabo-Etienne
    Synthesis of a ruthenium bis(diisopropylamino(isocyano)borane) complex from the activation of an amino(cyano)borane,
    Dalton Trans. 2013, 42, 776-781
  • Ulrike Helmstedt and Eric Clot
    Hydride Ligands Make the Difference, Density Functional Study of the Mechanism of the Murai Reaction Catalyzed by [Ru(H)2(H2)2(PR3)2] (R=cyclohexyl),
    Chem. Eur. J. 2012, 18, 11449-11458
  • Pei-Jen Tiong, Ainara Nova, Andrew D. Schwarz, Jonathan D. Selby, Eric Clot and Philip Mountford
    Site selectivity and reversibility in the reactions of titanium hydrazides with Si-H, Si-X, C-X and H+ reagents, Ti=Nα 1,2-silane addition, Nβ alkylation, Nα protonation and σ-bond metathesis,
    Dalton Trans. 2012, 41, 2277-2288
  • Paolo Larini, Christos E. Kefalidis, Rodolphe Jazzar, Alice Renaudat, Eric Clot and Olivier Baudoin
    On the Mechanism of the Palladium-Catalyzed β-Arylation of Ester Enolates,
    Chem. Eur. J. 2012, 18, 1932-1944
  • Andrew D. Schwarz, Ainara Nova, Eric Clot and Philip Mountford
    Titanium tert-Butoxyimido Compounds,
    Inorg. Chem. 2011, 50, 12155-12171
  • Yann Gloaguen, Gilles Alcaraz, Alban S. Petit, Eric Clot, Yannick Coppel, Laure Vendier and Sylviane Sabo-Etienne
    Ruthenium agostic (phosphinoaryl)borane complexes, multinuclear solid-state and solution NMR, X-ray and DFT studies,
    J. Am. Chem. Soc. 2011, 133, 17232-17238
  • Gaëtan Bénac-Lestrille, Ulrike Helmstedt, Laure Vendier, Gilles Alcaraz, Eric Clot and Sylviane Sabo-Etienne
    Dimethylaminoborane (H2BNMe2) coordination to late transition metal centers, snapshots of the B-H oxidative addition process,
    Inorg. Chem. 2011, 50, 11039-11045
  • Eric Clot, Odile Eisenstein, Naseralla Jasim, Stuart A. Macgregor, John E. Macgrady and Robin N. Perutz
    C-F and C-H Bond Activation of Fluorobenzenes and Fluoropyridines at Transition Metal Centers, How Fluorine Tips the Scales,
    Acc. Chem. Res. 2011, 44, 333-348
  • Andrew D. Schwarz, Ainara Nova, Eric Clot and Philip Mountford
    Titanium alkoxyimido (Ti=N-OR) complexes, reductive N-O bond cleavage at the boundary between hydrazide and peroxide ligands,
    Chem. Commun. 2011, 47, 4926-4928
  • Jonathan D. Selby, Marta Feliz, Andrew D. Schwarz, Eric Clot and Philip Mountford
    New Sandwich and Half-Sandwich Titanium Hydrazido Compounds,
    Organometallics 2011, 30, 2295-2307
  • Pei-Jen Tiong, Ainara Nova, Laura R. Groom, Andrew D. Schwarz, Jonathan D. Selby, A. Daniel Schofield, Eric Clot and Philip Mountford
    Reactions of Cyclopentadienyl-Amidinate Titanium Hydrazides with CO2, CS2, and Isocyanates, Ti=Nα Cycloaddition, Cycloaddition-Insertion, and Cycloaddition-NNR2 Group Transfer Reactions,
    Organometallics 2011, 30, 1182-1201
  • Pei-Jen Tiong, Ainara Nova, Eric Clot and Philip Mountford
    Si-H and Si-Cl bond activation reactions of titanium hydrazides with silanes and subsequent Ti-H/E-H (E = Si or H) σ-bond metathesis,
    Chem. Commun. 2011, 47, 3147-3149
  • A. Daniel Schofield, Ainara Nova, Jonathan D. Selby, Andrew D. Schwarz, Eric Clot and Philip Mountford
    Reaction site diversity in the reactions of titanium hydrazides with organic nitriles, isonitriles and isocyanates, Ti=Nα cycloaddition, Ti=Nα insertion and Nα-Nβ bond cleavage,
    Chem. Eur. J. 2011, 17, 265-285
  • Bradley M. Kraft, Eric Clot, Odile Eisenstein, William W. Brennessel and William D. Jones
    Mechanistic investigation of vinylic carbon-fluorine bond activation of perfluorinated cycloalkenes using Cp*2ZrH2 and Cp*2ZrHF,
    J. Fluorine Chem. 2010, 131, 1122-1132
  • Gilles Alcaraz, Adrian B. Chaplin, Charlotte J. Stevens, Eric Clot, Laure Vendier, Andrew S. Weller and Sylviane Sabo-Etienne
    Ruthenium, Rhodium, and Iridium Bis(σ-B-H) Diisopropylaminoborane Complexes+,
    Organometallics 2010, 29, 5591-5595
  • Taro Tanabe, William W. Brennessel, Eric Clot, Odile Eisenstein and William D. Jones
    Synthesis, structure, and reductive elimination in the series Tp'Rh(PR3)(ArF)H; Determination of rhodium-carbon bond energies of fluoroaryl substituents,
    Dalton Trans. 2010, 39, 10495-10509
  • Christos E. Kefalidis, Olivier Baudoin and Eric Clot
    DFT study of the mechanism of benzocyclobutene formation by palladium-catalysed C(sp3)-H activation, role of the nature of the base and the phosphine,
    Dalton Trans. 2010, 39, 10528-10535
  • Julie Guihaume, Eric Clot, Odile Eisenstein and Robin N. Perutz
    Importance of palladium-carbon bond energies in direct arylation of polyfluorinated benzenes,
    Dalton Trans. 2010, 39, 10510-10519
  • Alice Renaudat, Ludivine Jean-Gerard, Rodolphe Jazzar, Christos E. Kefalidis, Eric Clot and Olivier Baudoin
    Palladium-Catalyzed β-Arylation of Carboxylic Esters,
    Angew. Chem. Int. Ed. 2010, 49, 7261-7265
  • Sophie Rousseaux, Michaël Davi, Julien Sofack-Kreutzer, Cathleen Pierre, Christos E. Kefalidis, Eric Clot, Keith Fagnou and Olivier Baudoin
    Intramolecular Palladium-Catalyzed Alkane C-H Arylation from Aryl Chlorides,
    J. Am. Chem. Soc. 2010, 132, 10706-10716
  • A. Daniel Schofield, Ainara Nova, Jonathan D. Selby, Catherine D. Manley, Andrew D. Schwarz, Eric Clot and Philip Mountford
    M═Nα Cycloaddition and Nα−Nβ Insertion in the Reactions of Titanium Hydrazido Compounds with Alkynes: A Combined Experimental and Computational Study,
    J. Am. Chem. Soc. 2010, 132, 10484-10497
  • Céline Taffin, Glenda Kreutler, Damien Bourgeois, Eric Clot and Christian Perigaud
    Diels-Alder reaction of vinylene carbonate and 2,5-dimethylfuran, kinetic vs. thermodynamic control,
    New J. Chem. 2010, 34, 517-525
  • David Balcells, Eric Clot and Odile Eisenstein
    C-H bond activation in transition metal species from a computational perspective,
    Chem. Rev. 2010, 110, 749-823
  • Gilles Alcaraz, Laure Vendier, Eric Clot and Sylviane Sabo-Etienne
    Ruthenium bis(σ-B-H) aminoborane complexes from dehydrogenation of amine-boranes, trapping of H2B-NH2,
    Angew. Chem. Int. Ed. 2010, 49, 918-920
  • Pei-Jen Tiong, A. Daniel Schofield, Jonathan D. Selby, Ainara Nova, Eric Clot and Philip Mountford
    Single and double substrate insertion into the Ti=Nα bonds of terminal titanium hydrazides,
    Chem. Commun. 201085-87
  • John A. Blacker, Eric Clot, Simon B. Duckett, Odile Eisenstein, Jake Grace, Ainara Nova, Robin N. Perutz, David J. Taylor and Adrian C. Whitwood
    Synthesis and structure of "16-electron" rhodium(III) catalysts for transfer hydrogenation of a cyclic imine, mechanistic implications,
    Chem. Commun. 20096801-6803
  • Meagan E. Evans, Catherine L. Burke, Sornanong Yaibuathes, Eric Clot, Odile Eisenstein and William D. Jones
    Energetics of C-H Bond Activation of Fluorinated Aromatic Hydrocarbons Using a [Tp'Rh(CNneopentyl)] Complex,
    J. Am. Chem. Soc. 2009, 131, 13464-13473
  • Aldo E. Guiducci, Catherine L. Boyd, Eric Clot and Philip Mountford
    Reactions of cyclopentadienyl-amidinate titanium imido compounds with CO2: cycloaddition-extrusion versus cycloaddition-insertion,
    Dalton Trans. 20095960-5979
  • Eric Clot
    Ion-pairing in organometallic chemistry: structure and influence on proton transfer from a computational perspective,
    Eur. J. Inorg. Chem. 20092319-2328
  • Eric Clot, Claire Mégret, Odile Eisenstein and Robin N. Perutz
    Exceptional sensitivity of metal-aryl bond energies to ortho-fluorine substituents: influence of the metal, the coordination sphere, and the spectator ligands on M-C/H-C bond energy correlations,
    J. Am. Chem. Soc. 2009, 131, 7817-7827
  • Yann Gloaguen, Gilles Alcaraz, Anne-Frédérique Pécharman, Eric Clot, Laure Vendier and Sylviane Sabo-Etienne
    Phosphinoborane and sulfidoborohydride as chelating ligands in polyhydride ruthenium complexes, agostic σ-borane versus dihydroborate coordination,
    Angew. Chem. Int. Ed. 2009, 48, 2964-2968
  • Paul D. Bolton, Nico Adams, Eric Clot, Andrew R. Cowley, Paul J. Wilson, Martin Schröder and Philip Mountford
    Synthesis and ethylene polymerization capability of metallocene-like imido titanium dialkyl compounds and their reactions with AliBu3,
    Organometallics 2006, 25, 5549-5565
  • Gianluca Ciancaleoni, Cristiano Zuccaccia, Daniele Zuccaccia, Eric Clot and Alceo Macchioni
    Self-aggregation tendency of all species involved in the catalytic cycle of bifunctional transfer hydrogenation,
    Organometallics 2009, 28, 960-967
  • Jonathan D. Selby, Catherine D. Manley, Andrew D. Schwarz, Eric Clot and Philip Mountford
    Titanium Hydrazides Supported by Diamide-Amine and Related Ligands: A Combined Experimental and DFT Study,
    Organometallics 2008, 27, 6479-6494
  • Jonathan D. Selby, Christian Schulten, Andrew D. Schwarz, Andreas Stasch, Eric Clot, Cameron Jones and Philip Mountford
    Cycloaddition reactions of transition metal hydrazides with alkynes and heteroalkynes, coupling of Ti=NNPh2 with PhCCMe, PhCCH, MeCN and tBuCP,
    Chem. Commun. 20085101-5103
  • Marta Feliz, Paul Bolton, Philip Mountford and Eric Clot
    Ti=NR vs. Ti-R' functional group selectivity in imido titanium alkyl cations from a DFT perspective,
    Organometallics 2008, 27, 6111-6122
  • Manon Chaumontet, Riccardo Piccardi, Nicolas Audic, Julien Hitce, Jean-Louis Peglion, Eric Clot and Olivier Baudoin
    Synthesis of benzocyclobutenes by palladium-catalyzed C-H activation of methyl groups, method and mechanistic study,
    J. Am. Chem. Soc. 2008, 130, 15157-15166
  • Paul Bolton, Marta Feliz, Andrew R. Cowley, Eric Clot and Philip Mountford
    Ti=NR vs. Ti-R' functional group selectivity in imido titanium alkyl cations from an experimental perspective,
    Organometallics 2008, 27, 6096-6110
  • Gilles Alcaraz, Ulrike Helmstedt, Eric Clot, Laure Vendier and Sylviane Sabo-Etienne
    A terminal borylene ruthenium complex, from B-H activation to reversible hydrogen release,
    J. Am. Chem. Soc. 2008, 130, 12878-12879
  • Carmen R. Barone, Renzo Cini, Eric Clot, Odile Eisenstein, Luciana Maresca, Giovanni Natile and Gabriella Tamasi
    A NMR, X-ray, and DFT combined study on the regio-chemistry of nucleophilic addition to platinium(II) coordinated terminal olefins,
    J. Organomet. Chem. 2008, 693, 2819-2827
  • Helen R. Bigmore, Jens Meyer, Ivo Krummenacher, Heinz Rüegger, Eric Clot, Philip Mountford and Frank Breher
    Syntheses, Reactivity and DFT Studies of Group 2 and Group 12 Metal Complexes of Tris(pyrazolyl)methanides Featuring "Free" Pyramidal Carbanions,
    Chem. Eur. J. 2008, 14, 5918-5934
  • Cara S. Tredget, Eric Clot and Philip Mountford
    Synthesis, DFT Studies, and Reactions of Scandium and Yttrium Dialkyl Cations Containing Neutral fac-N3 and fac-S3 Donor Ligands,
    Organometallics 2008, 27, 3458-3473
  • David Balcells, Ainara Nova, Eric Clot, Dinakar Gnanamgari, Robert H. Crabtree and Odile Eisenstein
    Mechanism of Homogeneous Iridium-Catalyzed Alkylation of Amines with Alcohols from a DFT Study,
    Organometallics 2008, 27, 2529-2535
  • Anne-Marie Leduc, Alain Salameh, Daravong Soulivong, Mathieu Chabanas, Jean-Marie Basset, Christophe Copéret, Xavier Solans-Monfort, Eric Clot, Odile Eisenstein, Volker Böhm and Michael P W. Röper
    β-H transfer from the metallacyclobutane, a key step in the deactivation and byproduct formation for the well-defined silica-supported rhenium alkylidene alkene metathesis catalyst,
    J. Am. Chem. Soc. 2008, 130, 6288-6297
  • Macarena Poyatos, William Mcnamara, Christopher D. Incarvito, Eric Clot, Eduardo Peris and Robert H. Crabtree
    A weak donor, planar chelating bitriazole N-heterocyclic carbene ligand for ruthenium(II), palladium(II), and rhodium,
    Organometallics 2008, 27, 2128-2136
  • Frédéric Blanc, Jean-Marie Basset, Christophe Copéret, Amritanshu Sinha, Zachary J. Tonzetich, Richard R. Schrock, Xavier Solans-Monfort, Eric Clot, Odile Eisenstein, Anne Lesage and Lyndon Emsley
    Dynamics of silica-supported catalysts determined by combining solid-state NMR spectroscopy and DFT calculations,
    J. Am. Chem. Soc. 2008, 130, 5886-5900
  • Marius Câmpian, Eric Clot, Odile Eisenstein, Ulrike Helmstedt, Naseralla Jasim, Robin N. Perutz, Adrian C. Whitwood and David Williamson
    Stereochemical nonrigidity of a chiral rhodium boryl hydride complex, a σ-borane complexe as transition state for isomerization.,
    J. Am. Chem. Soc. 2008, 130, 4375-4385
  • Monica Viciano, Marta Feliz, Rosa Corberan, Jose Mata, Eric Clot and Eduardo Peris
    Aliphatic versus Aromatic C-H Activation in the Formation of Abnormal Carbenes with Iridium, A Combined Experimental and Theoretical Study,
    Organometallics 2007, 26, 5304-5314
  • Adelina M. Voutchkova, Marta Feliz, Eric Clot, Odile Eisenstein and Robert H. Crabtree
    Imidazolium Carboxylates as Versatile and Selective N-Heterocyclic Carbene Transfer Agents, Synthesis, Mechanism, and Applications,
    J. Am. Chem. Soc. 2007, 129, 12834-12846
  • Jonathan D. Selby, Catherine Manley, Marta Feliz, Andrew D. Schwarz, Eric Clot and Philip Mountford
    New ligand platforms for developing the chemistry of the Ti=N-NR2 functional group and the insertion of alkynes into the N-N bond of a Ti=N-NPh2 ligand,
    Chem. Commun. 20074937-4939
  • Gilles Alcaraz, Eric Clot, Ulrike Helmstedt, Laure Vendier and Sylviane Sabo-Etienne
    Mesitylborane as a Bis(σ-B-H) Ligand, An Unprecedented Bonding Mode to a Metal Center,
    J. Am. Chem. Soc. 2007, 129, 8704-8705
  • Daniele Zuccaccia, Gianfranco Bellachioma, Giuseppe Cardaci, Gianluca Ciancaleoni, Cristiano Zuccaccia, Eric Clot and Alceo Macchioni
    Interionic Structure of Ion Pairs and Ion Quadruples of Half-Sandwich Ruthenium(II) Salts Bearing -Diimine Ligands,
    Organometallics 2007, 26, 3930-3946
  • Albert Poater, Xavier Solans-Monfort, Eric Clot, Christophe Copéret and Odile Eisenstein
    Understanding d0-Olefin Metathesis Catalysts, Which Metal, Which Ligands?,
    J. Am. Chem. Soc. 2007, 129, 8207-8216
  • Eric Clot, Odile Eisenstein and Robert H. Crabtree
    Computational structure-activity relationships in H2 storage, how placement of N atoms affects release temperatures in organic liquid storage materials,
    Chem. Commun. 20072231-2233
  • Andrew Toner, Jochen Matthes, Stephan Gründemann, Hans-Heinrich Limbach, Bruno Chaudret, Eric Clot and Sylviane Sabo-Etienne
    Agostic interaction and intramolecular proton transfer from the protonation of dihydrogen ortho metalated ruthenium complexes,
    Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 6945-6950
  • Eric Clot, Odile Eisenstein and William D. Jones
    Structural and dynamic properties of propane coordinated to TpRh(CNR) from a confrontation between theory and experiment,
    Proc. Natl. Acad. Sci. U.S.A. 2007, 104, 6939-6944
  • Daniele Zuccaccia, Eric Clot and Alceo Macchioni
    Aggregation in solution of neutral half-sandwich Ru(II) precatalysts for transfer hydrogenation,
    New J. Chem. 2005, 29, 430-433
  • Catherine L. Boyd, Eric Clot, Aldo E. Guiducci and Philip Mountford
    Pendant arm functionalized benzamidinate titanium imido compounds: Experimental and computational studies of their reactions with CO2,
    Organometallics 2005, 24, 2347-2367
  • Benjamin D. Ward, Gavin Orde, Eric Clot, Andrew R. Cowley, Lutz H. Gade and Philip Mountford
    Reactions of neutral and cationic diamide-supported imido complexes with CO2 and other heterocumulenes: Issues of site selectivity,
    Organometallics 2005, 24, 2368-2385
  • Paul D. Bolton, Eric Clot, Andrew R. Cowley and Philip Mountford
    Well-defined imidotitanium alkyl cations: agostic interactions, migratory insertion vs. [2+2] cycloaddition, and the first structurally authenticated AlMe3 adduct of any transition metal alkyl cation,
    Chem. Commun. 20053313-3315
  • Sergio Alunni, Gianfranco Bellachioma, Eric Clot, Tiziana Del Giocco, Laura Ottavi and Daniele Zuccaccia
    Structure and reactivity of trans-bis[2-(2-chloroethyl)pyridine]palladium chloride (1). A study on the elimination reaction of 1 and 2-(2-chloroethyl)pyridine induced by quinuclidine in acetonitrile,
    J. Org. Chem. 2005, 70, 10688-10692
  • Paul D. Bolton, Eric Clot, Nico Adams, Stuart R. Dubberley, Andrew R. Cowley and Philip Mountford
    Experimental and DFT studies of cationic imido titanium alkyls: Agostic interactions and C-H bond and solvent activation reactions of isolobal analogues of group 4 metallocenium cations,
    Organometallics 2006, 25, 2806-2825
  • Hazel A. Sparkes, Paul R. Raithby, Eric Clot, Gregory P. Shields, James A. Chisholm and Frank H. Allen
    Carbonyl(center dot center dot center dot)carbonyl interactions in first-row transition metal complexes,
    CrystEngComm 2006, 8, 563-570
  • Paul D. Bolton, Eric Clot, Andrew R. Cowley and Philip Mountford
    AlMe3 and ZnMe2 adducts of an imido titanium methyl cation: a combined crystallographic, spectroscopic and DFT study,
    J. Am. Chem. Soc. 2006, 128, 15005-15018
  • Alvaro Aballay, Eric Clot, Odile Eisenstein, Maria Teresa Garland, Fernando Godoy, A. Hugo Klahn, Juan Carlos Muñoz and Beatriz Oelckers
    Selectivity in C–Cl bond activation of dichloroarenes by photogenerated Cp*Re(CO)2: combined experimental and DFT studies,
    New J. Chem. 2005, 29, 226-231
  • Albert Poater, Xavier Solans-Monfort, Eric Clot, Christophe Copéret and Odile Eisenstein
    DFT calculations of d0 M(NR)(CHtBu)(X)(Y) (M =Mo, W; R = CPh3,2,6-iPr–C6H3; X and Y = CH2tBu, OtBu, OSi(OtBu)3), olefin metathesis catalysts: structural, spectroscopic and electronic properties.,
    Dalton Trans. 20063077-3087
  • Xavier Solans-Monfort, Eric Clot, Christophe Copéret and Odile Eisenstein
    Understanding Structural and Dynamic Properties of Well-Defined Rhenium-Based Olefin Metathesis Catalysts, Re(CR)(CHR)(X)(Y), from DFT and QM/MM Calculations,
    Organometallics 2005, 24, 1586-1597
  • Leah N. Appelhans, Daniele Zuccaccia, Anes Kovacevic, Anthony R. Chianese, John R. Miecznikowski, Alceo Macchioni, Eric Clot, Odile Eisenstein and Robert H. Crabtree
    An Anion-Dependent Switch in Selectivity Results from a Change of C-H Activation Mechanism in the Reaction of an Imidazolium Salt with IrH5(PPh3)2,
    J. Am. Chem. Soc. 2005, 127, 16299-16311
  • Xavier Solans-Monfort, Eric Clot, Christophe Copéret and Odile Eisenstein
    d0 Re-Based Olefin Metathesis Catalysts, Re(CR)(CHR)(X)(Y): The Key Role of X and Y Ligands for Efficient Active Sites,
    J. Am. Chem. Soc. 2005, 127, 14015-14025
  • Eric Clot, Claire Mégret, Odile Eisenstein and Robin N. Perutz
    Validation of the M-C/H-C Bond Enthalpy Relationship through Application of Density Functional Theory,
    J. Am. Chem. Soc. 2006, 128, 8350-8357
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    Conférences Invitées

  • Eric Clot,
    DFT Studies of homogeneous catalytic reactions: Cu-catalyzed formation of amides from alcohol and amine
    ,
    «Gordon Research Conference: Organometallic Chemistry»,
    Newport, Etats-Unis, 10-15 juillet 2016,
  • Eric Clot,
    Reactivity of titanium-hydrazido complexes from a computational perspective
    ,
    «PACIFICHEM Meeting, Symposia on "Activation of Small Molecules by Electropositive Metals Related to Chemical Energy Conversion"»,
    Honolulu, Etats-Unis, 10-15 décembre 2015,
  • Eric Clot,
    Activation C-H catalytique: l'apport des études théoriques.
    ,
    «Journées Scientifiques 2013 de la Section Bretagne-Pays de la Loire de la SCF»,
    Brest, France, 05-07 mai 2013,
  • Eric Clot,
    Ruthenium-borane complexes: structure and reactivity from a computational perspective
    ,
    «XXVth International Conference on Organometallic Chemistry»,
    Lisbonne, Portugal, 2-7 septembre 2012,
  • Eric Clot,
    Ruthenium-Borane Complexes: Structure and Reactivity from a Computational Perspective
    ,
    «95th Canadian Chemistry Conference»,
    Calgary, Canada, 26-30 mai 2012,
  • Eric Clot,
    18-electron rule : myth or reality? A Natural Bond Orbital perspective.
    ,
    «8th International School of Organometallic Chemistry, ISOC2011»,
    Camerino, Italie, 27-31 août 2011,
  • Eric Clot, Christos KEFALIDIS,
    DFT Study of the mechanism of palladium-catalysed arylation of carboxylic esters.
    ,
    «9th Congress of the World Association of Theoretically Oriented Chemists, WATOC2011»,
    Saint Jacques de Compostelle, Espagne, 17-23 juillet 2011,
  • Eric Clot, Christos KEFALIDIS,
    DFT Study of the mechanism of PD-catalysed arylation of carboxylic esters.
    ,
    «3rd Chinese French Workshop in Theoretical Chemistry»,
    La Colle sur Loup, France, 10-12 octobre 2011,
  • Eric Clot,
    On the use of dispersion corrections in computational studies of transition metal reactivity
    ,
    «Challenges in Computational Homogeneous Catalysis»,
    Stockholm, Suède, 25-26 août 2011,
  • Eric Clot,
    C-H Activation in Homogeneous Catalysis from a Computational Perspective
    ,
    «Groupe d'Etude en Chimie Organique 51»,
    La Grande Motte, France, 01-05 septembre 2010,
  • Eric Clot,
    Transition Metal Catalyzed C-H Activation from a Computational Perspective'
    ,
    «Innovative Catalysis - New Processes and Selectivities»,
    Ankara, Turquie, 25-27 mai 2010,
  • Eric Clot,
    Modélisation de l'activation C-H en catalyse homogène: aspects thermodynamiques et cinétique
    ,
    «Journées Sherbrooke-Montpellier 2010»,
    Sherbrooke, Canada, 05-08 octobre 2010,
  • Eric Clot,
    Selectivity in C-H activation from a computational perspective
    ,
    «CERC3 Young Chemists' Workshop on catalytic C-H functionalization of organic molecules»,
    Lyon, France, 05-08 avril 2009,
  • Eric Clot,
    Apport de la méthode NBO en chimie organométallique
    ,
    «IX Journées Thématiques de Chimie Théorique»,
    Marseille, 01 mars 2007,
  • Eric Clot,
    Carbènes N-hétérocycliques en catalyse: l'apport du théoricien
    ,
    «GECOM-CONCOORD 2006»,
    Noirmoutier, France, 20-25 mai 2006,
  • Eric Clot,
    Counter Ion E ffects on Structure and Reactivity from a DFT Perspective
    ,
    «Molecular Crystal Engineering : Euroconference on Evaluations and Predictions of Solid State Materials Properties»,
    Helsinki, Finlande, 21-25 juin 2005,

  • Communications orales

  • Eric Clot,
    Reactivity of Titanium Hydrazido Complexes from a Computational Perspective

    «COST Carisma Meeting»,
    Ljubljana, Slovénie, 21-23 mars 2016,
  • Eric Clot,
    Reactivity of titanium-hydrazido complexes from a computational perspective

    «4th CARISMA Meeting»,
    Ljubljana, Slovénie, 21-23 mars 2016,
  • Eric Clot,
    Experimental and Computational Studies of C-H and N-H Bond Activation in Amido-Zirconium Complexes

    «Third CARISMA COST Action Meeting»,
    Tarragone, Espagne, 17-20 mars 2015,
  • Eric Clot,
    Anti-Markovnikov Hydroarylation of Unactivated Terminal, Internal, and Cyclic Olefins with Electron-poor Arenes

    «2nd International Symposium on C-H Activation»,
    Rennes, France, 1-5 juillet 2014,
  • Eric Clot,
    Anti-Markovnikov Hydroarylation of Unactivated Terminal, Internal, and Cyclic Olefins with Electron-poor Arenes

    «XXVI International Conference on Organometallic Chemistry»,
    Sapporo, Japon, 12-18 juillet 2014,
  • Eric Clot, Christos KEFALIDIS, Olivier Baudoin,
    DFT Study of the mechanism of benzocyclobutene formation by palladium-catalyzed C(sp3)-H activation: role of the nature of the base and the phosphine

    «Dalton Discussion 12 Catalytic C-H and C-X Bond Activation»,
    Durham, Angleterre, 12-15 septembre 2010,
  • Eric Clot, ,
    Selectivity in C-H activation from a computational perspective

    «38th Meeting of the RSC Inorganic Reaction Mechanisms Group»,
    Oxford, Angleterre, 04-06 janvier 2009,
  • Eric Clot, ,
    A terminal borylene ruthenium complex: from B-H activation to reversible hydrogen release

    «Innovative Catalysis - New Processes and Selectivities»,
    Turku, Finlande, 25-28 mai 2009,
  • Eric Clot, Ulrike Helmstedt, ,
    Selectivity in CH activation from a computational perspective

    «XXIII International Conference on Organometallic Chemistry»,
    Rennes, France, 13-18 juillet 2008,
  • Eric Clot,
    Influence of the counter anion in organometallic chemistry from a theoretical perspective

    «9th FIGIPAS»,
    Vienne, Autriche, 4-7 juillet 2007,
  • Eric Clot, Marta Feliz, P. D. Bolton, P. Mountford,
    Agostic interactions and heterobimetallic adducts in cationic imido and metallocenium titanium alkyls from a DFT perspective: analogies and differences."

    «XXIIth ICOMC»,
    Saragosse, Espagne, 23-28 juillet 2006,
  • Eric Clot,
    Theoretical studies of the structure and energetic of ion-pairs and higher order aggregates in transition metal complexes

    «Group Meeting COST D24»,
    Lisbonne, Portugal, 21-23 septembre 2006,

  • Activités d’Enseignement

    • DEUG Université Montpellier 2 : Préparation ENSI Chimie : Thermodynamique et Cinétique (1997-2000, 21h/an).
    • Préparation Agrégation de Physiques, Université Montpellier 2 : Cours Chimié Générale et Corrections Problèmes (1998-2000, 30h/an).
    • DEA PCMET, Université Paul Sabatier : Structure et Réactivité en Chimie Organométallique : Approche Théorique (1999-2002, 15h/an).
    • DEA PCT, Université Paul Sabatier : Chimie Théorique Appliquée à l’Etude de la Réactivité (1999-2000, 21h/an).
    • Agrégation de Chimie : Membre du Jury (2000-2005).
    • Ecole Polytechnique : Professeur Chargé de Cours (depuis 2004, 15h/an)

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